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Area of Science:

  • Materials Science
  • Nanotechnology
  • Physical Chemistry

Background:

  • Metal nanoclusters (MNCs) are atomically precise nanomaterials with unique electronic and optical properties.
  • Photothermal conversion, converting light to heat, is a key property of MNCs with diverse applications.

Purpose of the Study:

  • To review recent advancements in MNC synthesis strategies.
  • To analyze the photothermal conversion behaviors of various MNC systems.
  • To discuss challenges and future prospects in MNC-based photothermal technologies.

Main Methods:

  • Summary of advanced synthetic strategies: kinetic control, seeded growth, in situ two-phase ligand exchange, and metal exchange.
  • Comprehensive analysis of photothermal conversion in coinage metal, Ti, and Mo nanoclusters.
  • Discussion of structural characteristics, optical properties, and conversion mechanisms.

Main Results:

  • Novel synthetic methods address challenges like polydispersity and low yield.
  • Detailed understanding of photothermal conversion efficiencies and mechanisms in various MNCs.
  • Identification of structure-property relationships governing photothermal performance.

Conclusions:

  • Atomic-level engineering and interdisciplinary approaches are vital for advancing MNC photothermal technologies.
  • Continued research promises innovative breakthroughs in solar energy, therapy, and catalysis.
  • This review provides valuable insights for researchers in nanocluster science and photothermal applications.