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Preparation of Biomass-based Mesoporous Carbon with Higher Nitrogen-/Oxygen-chelating Adsorption for CuII Through Microwave Pre-Pyrolysis
Published on: February 12, 2019
Multifunctional copper sulfide nanoflowers for superior supercapacitors and microwave absorption
1School of Materials Science & Engineering, Jiangsu University, Zhenjiang, 212013, P. R. China. maiyongzhu@ujs.edu.cn.
Copper sulfide compounds show promise for energy storage and electromagnetic shielding. CuₓS-40 offers high capacitance, while CuₓS-60 excels in microwave absorption, highlighting dual applications.
Area of Science:
- Materials Science
- Electrochemistry
- Electromagnetics
Background:
- Developing multifunctional materials is crucial for advanced energy storage and electromagnetic shielding.
- Copper sulfide compounds offer compositional diversity and tunable morphology for these applications.
Purpose of the Study:
- To synthesize copper sulfide compounds with controlled morphologies using a hydrothermal method.
- To evaluate their performance in electrochemical energy storage and electromagnetic wave absorption.
Main Methods:
- Hydrothermal synthesis with adjustable solvent composition (ethylene glycol and water).
- Characterization using XRD, SEM, TEM, XPS, FTIR, and BET.
- Electrochemical testing in two-electrode and three-electrode configurations.
- Microwave absorption measurements.
Main Results:
- CuₓS-40 exhibited a specific capacitance of 796.6 F g⁻¹ at 1 A g⁻¹.
- CuₓS-40 demonstrated excellent cycling stability (100% retention after 5000 cycles at 10 A g⁻¹).
- CuₓS-60 achieved a minimum reflection loss of -43.20 dB with a 5.52 GHz effective absorption bandwidth.
Conclusions:
- Copper sulfide compounds possess significant potential for dual applications in energy storage and electromagnetic shielding.
- CuₓS-40 is effective for energy storage devices, powering an LED.
- CuₓS-60 shows excellent microwave absorption capabilities.
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