Related Experiment Video
Updated: May 2, 2026

A Technical Guide for Performing Spectroscopic Measurements on Metal-Organic Frameworks
Published on: April 28, 2023
Unlocking efficient near-infrared circularly polarized phosphorescence reaching 800 nm in cyclometalated Pt(II)
Shilin Gu1, Dongsheng Li1, Deng Long1
1Institute of Advanced Optoelectronic Materials and Technology, College of Big Data and Information Engineering, Guizhou University, Guiyang 550025, P. R. China. wtli@gzu.edu.cn.
None:
We report a promising strategy to design efficient NIR chiral Pt(II) complexes via ligand regulation and planar chirality formation, affording binuclear Pt(II) enantiomers that exhibit unprecedented NIR CPP reaching 800 nm, photoluminescence quantum yields of up to 35.4%, and luminescence dissymmetry factors of ∼3.9 × 10-3.
Related Concept Videos
Photoluminescence: Applications
Photochemical Electrocyclic Reactions: Stereochemistry
Selection Rules: Photochemical Activation
Variables Affecting Phosphorescence and Fluorescence
¹³C NMR: Distortionless Enhancement by Polarization Transfer (DEPT)
Insensitive Nuclei Enhanced by Polarization Transfer (INEPT)
Photoluminescence: Fluorescence and Phosphorescence
A pair of electrons in a...

