A Bi2WO6/ZIF-8 composite nanomaterial: enhanced photocatalytic performance
Huizhen Liu1,2, Yong Fan1, Jie-Hui Yu1,2
1College of Chemistry, Jilin University, Changchun, Jilin, 130012, China. jhyu@jlu.edu.cn.
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Photocatalytic technology has emerged as a research hotspot, with the selection of photocatalytic materials being crucial to its success. Bismuth tungstate exhibits excellent visible-light photocatalytic activity as a photocatalyst; however, its application in pollutant removal is constrained by its low specific surface area and rapid recombination of photogenerated carriers. This study employs a solvothermal method to synthesize Bi2WO6 materials and prepares a Bi2WO6/ZIF-8 composite nanomaterial to enhance the photocatalytic performance of bismuth tungstate. The structure and morphology of the catalysts were characterized using XRD, SEM, XPS, FTIR, and BET techniques. The photocatalytic properties were evaluated by measuring UV-vis diffuse reflectance spectra, photoluminescence, electrochemical impedance, and photocurrent density. The visible-light-driven catalytic degradation of bromocresol purple (BCP) was assessed. Results indicate the successful synthesis of the Bi2WO6/ZIF-8 composite nanomaterial, achieving a 94.65% degradation rate for BCP. Under visible light, the photocatalytic reaction rate constants of Bi2WO6/ZIF-8 were 3.91 times and 21.56 times higher than those of Bi2WO6 and ZIF-8, respectively. Consequently, the Bi2WO6/ZIF-8 composite nanomaterial can effectively remove dyes from wastewater.
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