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Updated: May 6, 2026

Electrochemically and Bioelectrochemically Induced Ammonium Recovery
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Steering Intermediate Coupling by Alkali-Metal Cations for Efficient Nitrate Electroreduction to Ammonia.

Xiaowen Liu1,2, Baoguang Mao1, Yuanqing Shen1

  • 1State Key Laboratory of Organic-Inorganic Composites, Beijing Key Laboratory of Intelligent Design and Manufacturing for Hydrogen Energy Materials, Beijing University of Chemical Technology, Beijing, China.

Angewandte Chemie (International Ed. in English)
|May 5, 2026
PubMed
Summary

Alkali-metal cations, particularly Na+, can significantly enhance electrocatalytic nitrate reduction (eNO3-RR) for ammonia synthesis. This electrolyte engineering approach optimizes interfacial conditions, boosting ammonia production efficiency.

Keywords:
alkali‐metal cationscation‐dependentelectrocatalytic nitrate reductionintensifying the local electric fieldrestructuring of interfacial water

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