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Revealing Buried Thermal Responses in Polymer Multilayers Using Photothermal Mirror Infrared Spectroscopy.

Yide Zhang1,2, Nelson G C Astrath1,3, Lena Neubauer1,2

  • 1Institute of Chemical Technologies and Analytics, Technische Universität Wien, Vienna, Austria.

Applied Spectroscopy
|May 5, 2026
PubMed
Summary
This summary is machine-generated.

The photothermal mirror infrared (PTM-IR) technique unexpectedly enhances signals with thicker overlayers, unlike conventional methods. This breakthrough allows for non-destructive depth-resolved characterization of buried layers in multilayer materials.

Keywords:
Green’s function modelingPTM-IRPhotothermal mirror infrareddepth-resolved spectroscopypolymer bilayers

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Area of Science:

  • Materials Science
  • Optics
  • Spectroscopy

Background:

  • Depth-resolved characterization of buried layers is vital for understanding multilayer material properties.
  • Conventional photothermal techniques face signal attenuation with increasing overlayer thickness.

Purpose of the Study:

  • To demonstrate that the photothermal mirror infrared (PTM-IR) technique shows enhanced signals with increasing overlayer thickness.
  • To develop a quantitative model for predicting photothermal signal behavior in multilayer systems.
  • To establish PTM-IR as a tool for non-destructive subsurface characterization.

Main Methods:

  • Combined finite-element analysis (FEA) and one-dimensional analytical modeling using Green's function formalism.
  • Experimental validation using poly(methyl methacrylate)-polystyrene (PMMA-PS) bilayers on CaF2 substrates.
  • Photothermal Mirror Infrared (PTM-IR) spectroscopy.

Main Results:

  • PTM-IR signal transient increases with overlayer thickness due to enhanced thermal confinement and surface displacement.
  • FEA and analytical models accurately predict temperature and surface displacement dynamics.
  • Excellent agreement between experimental measurements and theoretical predictions was achieved.

Conclusions:

  • PTM-IR is a non-destructive infrared technique for probing buried absorbers.
  • The technique allows for the determination of both absorber and overlayer thicknesses.
  • PTM-IR extends the capabilities of photothermal methods for deeper subsurface characterization.