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Facile Preparation of Internally Self-assembled Lipid Particles Stabilized by Carbon Nanotubes
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Engineered Nanoparticles with Improved Foamability for Solely Stabilizing Pickering CO2 Foam.

Jie Lin1, Haizhu Wang2, Shuangxing Liu3

  • 1School of Advanced Materials, Peking University Shenzhen Graduate School, Shenzhen 518055, China.

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Surfactant-tailored nanoparticles create stable CO2 Pickering foams for enhanced carbon sequestration. This new foam technology outperforms classical and mixed foams under harsh conditions, improving safety and efficiency in saline aquifers.

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Area of Science:

  • Geochemistry
  • Materials Science
  • Chemical Engineering

Background:

  • Carbon dioxide (CO2) foam injection is vital for safe CO2 sequestration in saline aquifers.
  • Classical and mixed foams face stability issues under reservoir conditions due to surfactant limitations.

Purpose of the Study:

  • To develop and evaluate surfactant-tailored nanoparticles for stabilizing CO2 Pickering foams.
  • To overcome the limitations of existing foam stabilization methods for CO2 sequestration.

Main Methods:

  • Synthesis of surfactant-tailored nanoparticles.
  • Systematic foam stability evaluation (half-life, bubble size, interfacial film thickness).
  • Thin-film drainage modeling incorporating hydrodynamic flow and adsorption energetics.

Main Results:

  • Pickering foam demonstrated significantly higher foamability and stability than classical and mixed foams.
  • Enhanced stability observed across a broader range of conditions, including high temperature, salinity, and hydrocarbons.
  • Microscopic analysis revealed smaller, uniform bubbles, slower coarsening, and thicker interfacial films in Pickering foam.

Conclusions:

  • Surfactant-tailored nanoparticles effectively stabilize CO2 Pickering foams independently of free surfactants.
  • This approach offers a robust strategy for designing foam stabilizers for subsurface CO2 sequestration.
  • The findings pave the way for improved safety and efficiency in carbon capture and storage technologies.