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Nanobubbles by hybrid electro-membrane method: ROS quantification and utilization in complex wastewater treatment.

Gaurav Yadav1, Harsh Sharma1, Nilanjan Dutta1

  • 1Department of Chemical Engineering, Indian Institute of Technology Ropar, Rupnagar, 140001, Punjab, India.

Journal of Hazardous Materials
|May 9, 2026
PubMed
Summary
This summary is machine-generated.

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This study compares nanobubble (NB) generation methods for advanced oxidation processes (AOPs). A hybrid electro-membrane system enhanced reactive oxygen species (ROS) generation and contaminant degradation, showing promise for wastewater treatment.

Area of Science:

  • Environmental Science
  • Chemical Engineering
  • Materials Science

Background:

  • Nanobubbles (NBs) offer enhanced interfacial properties for advanced oxidation processes (AOPs).
  • Limited mechanistic understanding exists regarding reactive oxygen species (ROS) generation and treatment performance across different NB strategies.
  • Optimizing NB generation is crucial for intensifying AOPs and improving contaminant removal.

Purpose of the Study:

  • To systematically compare major NB generation methods based on NB characteristics, mass transfer, and ROS production.
  • To investigate the potential of a hybrid electro-membrane nanobubble (HEM-NB) system for enhanced AOPs.
  • To evaluate the degradation efficiency of the HEM-NB system using tannic acid in complex matrices.

Main Methods:

Keywords:
ElectrolysisGas–liquid mass transferRadicalsTannic acidUltrafine bubble

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  • Systematic comparison of NB generation techniques (electrochemical, membrane, gas-based).
  • Characterization of NB properties, gas-liquid mass transfer, and ROS quantification using fluorescence diagnostics.
  • Engineering and testing of a hybrid electro-membrane nanobubble (HEM-NB) system.
  • Application studies for tannic acid degradation in single and complex matrices.
  • Main Results:

    • Electromechanically reactive nanobubbles (ERNBs) showed high ROS activity but limited mass transfer.
    • Membrane-derived NBs offered high mass transfer with lower ROS yields.
    • The engineered HEM-NB system demonstrated higher NB density, enhanced mass transfer, and increased ROS availability.
    • HEM-NB treatment significantly improved tannic acid degradation kinetics in complex matrices, showing synergistic effects.

    Conclusions:

    • Mechanistic-performance linkages were established for different NB generation strategies.
    • The hybrid NB technology exhibits enhanced oxidative robustness for treating chemically complex effluents.
    • HEM-NB systems present a promising approach for intensifying AOPs and wastewater treatment.