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Updated: May 12, 2026

In situ FTIR Spectroscopy as a Tool for Investigation of Gas/Solid Interaction: Water-Enhanced CO2 Adsorption in UiO-66 Metal-Organic Framework
Published on: February 1, 2020
Linker-curvature stabilized Zn-rod framework with inverted C2 hydrocarbon adsorption
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Zn-based rod MOFs are fundamentally limited by Zn-O lability and activation-induced structural collapse, accounting for their scarcity. Here, linker curvature rigidifies Zn-rod secondary building units in NTUniv-69A, preventing pore collapse. The framework overturns the conventional C2 hydrocarbon adsorption hierarchy (C2H2 > C2H6 > C2H4), enabling single-step ethylene purification.
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