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Related Concept Videos

Metal-Ligand Bonds02:51

Metal-Ligand Bonds

The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...

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Related Experiment Video

Updated: May 13, 2026

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance
08:12

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance

Published on: September 5, 2018

A Robust Metal-Organic Framework Derived Bioinspired Metal-Polyphenol Network Interface for Enhanced Sodium Storage.

Zhilong Yan1, Zhiwen Long1, Keliang Wang2

  • 1Key Laboratory of Special Protective Textiles, Ministry of Education, College of Textile Science and Engineering, Jiangnan University, Wuxi, China.

Small (Weinheim an Der Bergstrasse, Germany)
|May 12, 2026
PubMed
Summary
This summary is machine-generated.

Flexible anode materials for sodium-ion batteries (SIBs) were developed using a bionic metal-phenolic network (MPN) strategy. This approach enhances interfacial stability and mechanical properties for wearable electronics.

Keywords:
carbonized silk textilemetal‐organic frameworkmetal‐polyphenol networkrobust interfacesodium storage

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Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
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Area of Science:

  • Materials Science
  • Electrochemistry
  • Nanotechnology

Background:

  • Flexible anode materials are essential for next-generation flexible and wearable electronics.
  • Current flexible current collectors for sodium-ion batteries (SIBs) exhibit poor interfacial stability and mechanical properties.

Purpose of the Study:

  • To develop a novel flexible anode material with enhanced interfacial stability and mechanical properties for SIBs.
  • To utilize a bionic metal-phenolic network (MPN) strategy inspired by biomineralization principles for interfacial engineering.

Main Methods:

  • A one-step calcination-sulfidation treatment was applied to a metal-organic framework (MOF) precursor on a flexible substrate.
  • The MOF precursor was transformed into Fe7S8 nanoparticles anchored on carbonized silk fabric.
  • A bionic MPN was formed via coordination between tannic acid and Fe3+ to direct MOF growth and create a carbon interlayer.

Main Results:

  • The optimized MSMF-2 composite demonstrated excellent structural integrity after 2000 bending cycles.
  • It achieved a specific areal capacity of 1.40 mAh cm-2 after 200 cycles and 97.3% capacity retention after 1000 cycles.
  • Stable interfacial passivation and dual intercalation-conversion storage behavior were observed.

Conclusions:

  • The bionic MPN strategy effectively integrates MOF-derived active materials for flexible SIB anodes.
  • This approach offers a promising solution for developing high-performance flexible energy storage devices.
  • The study highlights the potential of biomimetic interfacial regulation in advanced materials design.