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Related Concept Videos

Solid–Solid Solutions01:24

Solid–Solid Solutions

The temperature-composition phase diagram of two solids, A and B, which are immiscible in the solid phase but form miscible liquids, shows that when the temperature is low, these two exist as separate, pure solids (A and B). As the temperature increases, they transition into a single-phase liquid solution where A and B coexist. Moving from point a1 to a2 in the phase diagram, the composition changes such that solid B begins to separate from the solution, enriching the remaining liquid with A.
Phase Diagrams02:39

Phase Diagrams

A phase diagram combines plots of pressure versus temperature for the liquid-gas, solid-liquid, and solid-gas phase-transition equilibria of a substance. These diagrams indicate the physical states that exist under specific conditions of pressure and temperature and also provide the pressure dependence of the phase-transition temperatures (melting points, sublimation points, boiling points). Regions or areas labeled solid, liquid, and gas represent single phases, while lines or curves represent...
Recrystallization: Solid–Solution Equilibria01:10

Recrystallization: Solid–Solution Equilibria

Recrystallization is a purification technique used to separate impurities from solid compounds. In this technique, no chemical reactions occur. Instead, it exploits physical properties only, specifically, the solubility differences between the desired compound and impurities, either at a single temperature or at different temperatures, and under other selected conditions. The solid-solution equilibrium (solubility equilibrium) of each component in the solution represents a binary phase...
Precipitation of Ions03:11

Precipitation of Ions

Predicting Precipitation
The equation that describes the equilibrium between solid calcium carbonate and its solvated ions is:
Two Components: Liquid–Liquid Systems01:27

Two Components: Liquid–Liquid Systems

A pressure-composition phase diagram explicitly describes the behavior of an ideal solution of two volatile liquids under varying pressures and compositions. A pressure-composition diagram has two main curves. The bubble point curve represents the plot of pressure versus liquid mole fraction. It indicates the pressure at which the first bubble of vapor forms from the liquid phase as the system pressure decreases.The dew point curve is the pressure versus vapor mole fraction. It indicates the...
Liquid–Solid Solutions01:29

Liquid–Solid Solutions

The process of a solid dissolving in a liquid to form a solution is governed by the solubility limit, which is the maximum amount of the solid substance, or solute, that can be dissolved in a specific volume of the liquid or solvent. As the solute dissolves, it reaches a point where no more solute can be dissolved at a given temperature - this is known as the saturation point. However, if further solute is added and it manages to dissolve, the solution becomes supersaturated. Supersaturated...

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From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
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Formation Process and Solid-Liquid Phase Equilibrium of Cs(Cl, Br) Solid Solutions in Aqueous Solution.

Ya-Li Wang1,2, Rui-Zhi Cui1, Hong-Bao Ren1

  • 1Key Laboratory of Green and High-end Utilization of Salt Lake Resources, Qinghai Provincial Key Laboratory of Resources and Chemistry of Salt Lakes, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining, Qinghai 810008, China.

The Journal of Physical Chemistry. B
|May 19, 2026
PubMed
Summary
This summary is machine-generated.

This study explores cesium chloride-cesium bromide-water phase behavior at 298.15 K. It reveals solid solution formation and equilibrium, aiding cesium precipitation prediction in mixed halide systems.

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Area of Science:

  • Geochemistry
  • Materials Science
  • Physical Chemistry

Background:

  • Understanding cesium behavior is crucial for managing nuclear waste and industrial processes.
  • Cesium's complex interactions in mixed halide solutions require detailed investigation.

Purpose of the Study:

  • To investigate the formation of cesium chloride-cesium bromide solid solutions.
  • To determine the solid-liquid phase equilibrium in the CsCl-CsBr-H2O system at 298.15 K.
  • To provide a theoretical basis for predicting cesium precipitation.

Main Methods:

  • Multiscale study combining long-term experiments and molecular dynamics simulations.
  • Isothermal dissolution equilibrium method to determine phase relationships.
  • Pitzer model parametrization using experimental thermodynamic data.

Main Results:

  • Characterization of Cs(Cl, Br) solid solution formation.
  • Systematic determination of phase equilibrium and construction of a phase diagram.
  • Validation of the Pitzer model for solubility calculations.

Conclusions:

  • The study elucidates the formation and equilibrium of cesium solid solutions in mixed halide systems.
  • Experimental and modeled solubility data provide a basis for predicting cesium behavior.
  • This research offers insights into cesium precipitation dynamics relevant to environmental and industrial applications.