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In Situ Hydrogenation Strategy for Ultrahigh-Power Magnesium-Air Batteries.

Yongan Li1, Wenbin Jiang1, Bingnan Cai1

  • 1School of Materials Science and Engineering, Guangdong Provincial Key Laboratory of Advanced Energy Storage Materials, South China University of Technology, Guangzhou, 510641, P. R. China.

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Summary

Engineers developed a new magnesium-air battery using cerium hydride nanodomains. This innovation prevents passivation, enabling high energy and power density even at extreme current densities and temperatures.

Keywords:
cerium hydridehydrogenation-driven activationmagnesium-air batteryultrahigh-power dischargeweak-cathode phase

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Area of Science:

  • Electrochemistry
  • Materials Science
  • Energy Storage

Background:

  • Magnesium-air batteries offer high energy density and safety.
  • Rapid passivation of magnesium anodes hinders their practical application.

Purpose of the Study:

  • To develop a strategy to overcome passivation in magnesium-air batteries.
  • To enhance the kinetics and stability of magnesium anodes under high current densities.

Main Methods:

  • An in situ hydrogenation strategy was employed to embed cerium hydride (CeH2.73) nanodomains within magnesium.
  • The hydride-oxide conversion mechanism was investigated during battery discharge.
  • Performance was evaluated under ultrahigh current densities and varying temperatures (0 °C, 80 °C).

Main Results:

  • The CeH2.73 nanodomains reprogrammed magnesium dissolution from localized corrosion to a uniform mode.
  • A dynamic hydride-oxide conversion prevented passivation, enabling rapid interfacial turnover and efficient ion/electron transport.
  • The CeH2.73|Mg anode achieved an energy density of 396 Wh kg-1 and peak power density of 140 mW cm-2 at 200 mA cm-2.
  • Stable operation was demonstrated across a wide temperature range and in low-oxygen seawater environments.

Conclusions:

  • Hydride phase engineering is a generalizable strategy for high-power, wide-temperature metal-air energy systems.
  • The developed anode exhibits superior performance for demanding applications, including seawater batteries.