Related Experiment Video
Updated: May 23, 2026
Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
A quinazolinone-linked covalent organic framework with an intrinsic N-N bond for efficient palladium nanocatalysis
Xu-Hao Zhang1, Xiu-Hao Zhang1, Fu-Hao Liu1
1College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University, Jinan 250014, P. R. China. gengyan@sdnu.edu.cn.
Abstract:
We report a quinazolinone-linked covalent organic framework (AABH-TFBT-COF) featuring an intrinsic N-N bond embedded within the heterocyclic backbone. This framework stabilizes Pd nanoparticles and serves as a highly active and recyclable catalyst for Suzuki-Miyaura cross-coupling, highlighting the potential of heterocycle-embedded N-N linkages in heterogeneous catalysis.
