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Related Concept Videos

Weak Acid Solutions04:02

Weak Acid Solutions

Few compounds act as strong acids. A far greater number of compounds behave as weak acids and only partially react with water, leaving a large majority of dissolved molecules in their original form and generating a relatively small amount of hydronium ions. Weak acids are commonly encountered in nature, being the substances partly responsible for the tangy taste of citrus fruits, the stinging sensation of insect bites, and the unpleasant smells associated with body odor. A familiar example of a...
Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions.
Electrolysis03:00

Electrolysis

In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
Batteries and Fuel Cells03:12

Batteries and Fuel Cells

A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
Types of Reversible Electrodes01:24

Types of Reversible Electrodes

For electrode reversibility to be maintained, all the reactants and products involved in the half-reaction must be present at the electrode. There are several types of reversible electrodes (half-cells).In metal-metal-ion electrodes, a metal balances electrochemically with a solution of its own ions. Examples are Cu2+|Cu and Zn2+|Zn. Metals that react with the solvent, like group 1 and most group 2 metals, which react with water, and zinc, which reacts with aqueous acidic solutions, cannot be...

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Updated: May 26, 2026

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

Published on: August 12, 2013

Deciphering Emergent Oxyhalide Solid-State Electrolytes for Next-Generation All-Solid-State Lithium Metal Batteries.

Zhouwei Tan1,2, Zuxin Long2, Liansheng Li2

  • 1School of Rare Earth, University of Science and Technology of China, Hefei, Anhui, China.

Small (Weinheim an Der Bergstrasse, Germany)
|May 25, 2026
PubMed
Summary

Oxyhalide solid-state electrolytes offer a safer alternative to conventional lithium-ion batteries. This review explores their development and application in all-solid-state lithium metal batteries.

Keywords:
all‐solid‐state lithium metal batteriesdesign strategyhigh energy densityionic conductivityoxyhalide solid‐state electrolytes

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Screening of Coatings for an All-Solid-State Battery Using In Situ Transmission Electron Microscopy
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Last Updated: May 26, 2026

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Screening of Coatings for an All-Solid-State Battery Using In Situ Transmission Electron Microscopy

Published on: January 20, 2023

Area of Science:

  • Materials Science
  • Electrochemistry
  • Energy Storage

Background:

  • Conventional lithium-ion batteries pose safety risks due to flammable electrolytes and limited energy density.
  • All-solid-state lithium metal batteries (ASSLMBs) offer enhanced safety and energy density using solid-state electrolytes (SSEs) and lithium metal anodes.
  • Halide SSEs show promise but suffer from hygroscopicity and interfacial issues, necessitating improved materials.

Purpose of the Study:

  • To systematically review recent advancements in oxyhalide SSEs for ASSLMBs.
  • To focus on Li─M─ -O─Cl systems, analyzing their development, synthesis, and ion transport.
  • To evaluate strategies for improving stability and performance, and discuss battery-level applications.

Main Methods:

  • Literature review of recent research on oxyhalide SSEs.
  • Analysis of synthesis methods and structural classifications.
  • Evaluation of ion transport mechanisms in crystalline and amorphous states.
  • Assessment of design strategies for enhanced properties and interfacial chemistry.

Main Results:

  • Oxyhalide SSEs integrate oxygen into halide structures, improving electrochemical properties over traditional halides.
  • Development focuses on Li─M─ -O─Cl systems, with analysis of ion transport in various states.
  • Strategies for enhancing humidity stability, electrochemical window, and mechanical robustness are identified.
  • Interfacial chemistry and microstructural control are crucial for battery performance.

Conclusions:

  • Oxyhalide SSEs represent a promising pathway for safer and higher-performance ASSLMBs.
  • Further research is needed to address challenges in humidity stability, ionic conductivity, and interfacial engineering.
  • Optimizing material design and understanding interfacial phenomena are key to practical implementation.