Supramolecular Assembly of Plant Cell Wall-Derived Cellulose Nanosheets with Polyacrylamide for Sustainable Sand...

To address the global challenge of desertification, it is essential to develop sustainable and biodegradable materials for sand fixation to support ecological restoration in arid regions. In this work, a CNS/PAM biocomposite system was constructed through the supramolecular assembly of highly flexible two-dimensional cellulose nanosheets (CNS) and polyacrylamide (PAM). Benefiting from the flexible layered structure of CNS and the abundant hydroxyl and carboxyl groups on their surface, a conformal coating and an interparticle bridging network were formed via hydrogen bonding and coordination interactions with mineral cations. The introduction of PAM further regulated the hydrogen-bonding network, which improved structural uniformity and mechanical integrity. The resulting composites showed strong resistance to both wind and water erosion (erosion loss < 0.1%) and reached a compressive strength of up to 0.23 MPa, while maintaining good environmental compatibility. This study clarifies the structure-interaction-property relationships of cellulose nanosheet-based supramolecular assemblies and provides a new theoretical basis and practical pathway for designing biodegradable sand-fixing materials.