Wetting Behavior of Acrylate Hot-Melt Adhesive on Polyester Fabric Substrates and Its Influence on Adhesion...

Acrylate hot-melt adhesives (AHMAs) are widely used in medical dressings, electronic components, and automotive interiors due to their solvent-free nature and high bonding strength. However, their wetting behavior on porous fabric substrates under varying coating temperatures-a critical factor for interfacial adhesion-remains poorly understood. To investigate how coating temperature affects the wetting and adhesion of acrylic hot-melt adhesives on fabric substrates, the apparent surface tension and viscosity of the adhesive (130-160 °C) and the apparent surface energy of the substrate (20-160 °C) were measured. By combining these measurements with contact angle decay curves on steel plates, scanning electron microscopy of cold-brittle cross-sections, and mechanical property tests, the study analysed the effects of temperature on wetting and spreading, penetration depth, and adhesive performance. Results show that with increasing temperature, adhesive surface tension and viscosity decrease, while fluidity improves; substrate surface energy shows no temperature dependence. The penetration depth into the fabric increases from 16 μm to 25 μm, and penetration uniformity gradually improves. However, both peel strength and loop tack continuously decrease with rising temperature, with optimal adhesion at 130 °C. A penetration depth model based on the Washburn equation effectively predicts the penetration behavior. Viscosity accounts for more than 50% of the effect, whilst the wetting factor contributes to a lesser extent. This study provides a theoretical basis for optimizing the coating process of acrylic hot-melt adhesives on fabric substrates.