Related Experiment Video

Updated: May 31, 2026

Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes
12:27

Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes

Published on: September 8, 2013

Combining Ag(II) and Ag(I) Reactivity Enables Electrophotochemical Acyl Fluoride Installation on (Hetero)Arenes

Elaine Reichert Raguram1, Brandon M Campbell1, Jesse B Gordon1

  • 1Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, United States.

Journal of the American Chemical Society
|May 29, 2026
PubMed
Summary

This study introduces a novel electrophotocatalytic method using dual silver oxidation states to directly convert arenes into valuable acyl fluorides and perfluoroalkylated products. The process is efficient, tolerant of air and moisture, and recycles the silver catalyst.

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