Changing pH, organic matter, and redox state govern contaminant mobility during waste stabilization in landfill...

Landfills remain an important endpoint for waste and waste residues, yet current management in the Netherlands requires eternal aftercare to protect public health and the environment. Enhanced waste stabilization in landfills through active treatment, i.e. aeration and leachate recirculation, has potential as a sustainable alternative to current landfill management. However, the influence of active treatment on solid waste properties and subsequent leaching of hazardous contaminants has only received limited investigation. This study investigates these influences in landfill simulation reactors containing 30 kg of waste from different origins, which were treated using aeration, leachate recirculation, and their combination. Large differences in leachate contaminant concentrations were found between treatments. A shift from leachate recirculation to aeration changed prevailing redox conditions from anaerobic to aerobic and decreased pH and dissolved organic and inorganic carbon. Consequently, concentrations of ammonium and inorganic contaminants with a high organic matter binding affinity decreased, whereas other inorganic contaminants first increased in concentration due to mineral dissolution followed by a decrease due to mineral precipitation or binding to reactive surfaces. The underlying mechanisms of these trends were identified based on geochemical modelling. The observed changes during aeration were accelerated when aeration was preceded by leachate recirculation, and concentrations rebounded when anaerobic conditions were reintroduced. Our findings ultimately demonstrate that active treatment of landfills requires careful consideration of the most effective strategy, as trade-offs in contaminant leaching mean their potential risks should be weighed against each other.