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Batteries and Fuel Cells03:12

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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...

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A Simple and Scalable Fabrication Method for Organic Electronic Devices on Textiles
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Energetic All-Polymer Fiber Batteries Enabled by Interface-Interlocked Water-In-Network Electrolytes for Wearable

Kangkang Jia1, Qimin Liang1, Yang Hong2

  • 1School of Science, Harbin Institute of Technology (Shenzhen), Shenzhen, China.

Advanced Materials (Deerfield Beach, Fla.)
|June 2, 2026
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Summary

Researchers developed a novel "water-in-network" electrolyte for safer, sustainable all-polymer sodium-ion fiber batteries. This innovation enhances electrochemical stability and mechanical integrity for flexible electronics and wearable health monitoring.

Keywords:
all‐polymer batteryaqueous quasi‐solid polymer electrolytepolymer networkwater confinementwearable electronics

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Polymer Science

Background:

  • All-polymer fiber batteries offer safety and sustainability for wearables.
  • Current limitations include narrow electrochemical stability windows and interface instability.

Purpose of the Study:

  • To engineer a novel electrolyte for improved performance in all-polymer fiber batteries.
  • To address challenges in electrochemical stability and mechanical robustness.

Main Methods:

  • Developed a "water-in-network" (WIN) electrolyte by modulating polymer network crosslinking density.
  • Investigated the effect of crosslinking on water activity and dynamics.
  • Utilized in situ interfacial polymerization to create mechanically interlocked interfaces.

Main Results:

  • Discovered a "water confinement" effect influencing water activity non-monotonically with crosslinking density.
  • Achieved a significantly expanded electrochemical stability window of 3.4 V.
  • Demonstrated an energy density of 92.4 Wh kg⁻¹ for the sodium-ion fiber battery.
  • Maintained 78% capacity after 12,000 bending cycles due to suppressed delamination.
  • Successfully powered a fabric-based chemical sensor for on-body health monitoring.

Conclusions:

  • The WIN electrolyte effectively enhances electrochemical and mechanical stability in all-polymer fiber batteries.
  • This technology enables robust, flexible energy storage solutions for advanced wearable applications.
  • The developed batteries are suitable for powering integrated sensors in smart textiles for real-time health monitoring.