Related Experiment Video
Updated: Jun 5, 2026
Visualizing Uniaxial-strain Manipulation of Antiferromagnetic Domains in Fe1+YTe Using a Spin-polarized Scanning Tunneling Microscope
Published on: March 24, 2019
Tunable itinerant ferromagnetism in two-dimensional FePd2Te2 hosting 1D spin chains
Alberto M Ruiz1, Andrei Shumilin1, Sourav Dey1
1Instituto de Ciencia Molecular, Universitat de València, Catedrático José Beltrán 2, 46980 Paterna, Spain.
Abstract:
One-dimensional (1D) magnetism offers unidirectional spin interactions that allow unique tunable properties and unconventional spin phenomena. However, it often suffers from poor stability, limiting practical applications. In this regard, integrating 1D magnetism into two-dimensional (2D) materials enables a promising route to stabilize these systems while preserving their anisotropic magnetic characteristics. Here, we focus on the 2D ferromagnet FePd2Te2 (TC = 183 K), which hosts 1D spin chains and strong in-plane anisotropy. Our first-principles calculations reveal highly anisotropic magnetic exchange interactions, confirming its 1D ferromagnetic nature. We modulate this behavior by Co and Ni substitution and introduce two new members of this family: CoPd2Te2 (a ferromagnet) and NiPd2Te2. Our results unveil the microscopic mechanisms governing the behavior of FePd2Te2 and CoPd2Te2. Furthermore, we also demonstrate that the variation of the chain length is key to modulating magnetism. Finally, we determine the magnon dispersion, showcasing a pronounced anisotropy that enables unidirectional magnon propagation.
Related Concept Videos
01:31Ferromagnetism
02:42Valence Bond Theory
03:02Colors and Magnetism
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human eye.
02:46Crystal Field Theory - Tetrahedral and Square Planar Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
02:58Crystal Field Theory - Octahedral Complexes
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
01:12Two-Dimensional (2D) NMR: Overview
The first step is the preparation period, during which nucleus A is excited with a radiofrequency pulse.