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Water in Triple-Bond-Based Polymerizations: Roles as a Solvent or Monomer
Die Huang1, Anjun Qin1, Ben Zhong Tang2,3
1State Key Laboratory of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates, Center for Aggregation-Induced Emission, South China University of Technology, Guangzhou, 510640, China.
None:
Water, characterized by its safety, abundance, low cost, and sustainability, has garnered increasing attention in polymer synthesis. It has been utilized as a solvent or a co-monomer in polymerizations based on triple-bond building blocks for the construction of functional polymers. Currently, distinct progress has been made; however, no such review was presented. This Review aims to summarize the progress in alkyne-based polymerizations in aqueous media with the "on-water" effect, water-involved alkyne-based polymerizations, and water-involved isocyanide-based polymerizations. The catalyst systems, reaction conditions, post-modification strategies, and the properties and applications of the resulting polymers are summarized. Furthermore, the challenges and opportunities in this field are briefly discussed.
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