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Updated: Jun 12, 2026

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
Published on: November 21, 2017
Controlled Generation of Aldehydes or Carboxylic Acids Driven by Mn-Doped NiO
Jiaxiu Liu1, Jingye Fu1, Weisi Guo1
1College of Chemistry and Molecular Engineering, Qingdao University of Science & Technology, Qingdao 266042, China.
Abstract:
Controlling the oxidation of alcohols to form aldehydes, ketones, and carboxylic acids is a fundamental reaction in organic synthesis. This paper reports a method for oxidizing alcohols using chemically modified electrodes, where the reaction environment is altered to control the product formation. This approach is characterized by its green and mild nature, eliminating the need for oxidizing agents and offering simple operation while achieving high yields and good functional group tolerance. A series of control experiments elucidated the mechanism for this reaction.
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