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Related Experiment Video

Updated: Jun 12, 2026

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Processing-Enhanced β-Phase Formation in BaTiO3/PVDF Composite Fibers with High Electroactive Phase Content.

Marouene Ben Ouali1, Anik Das2, Chayma Ben Harrath1

  • 1School of Textile Science and Engineering, Tiangong University, Tianjin 300387, China.

Nanomaterials (Basel, Switzerland)
|June 11, 2026
PubMed
Summary

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Flexible piezoelectric fibers made from BaTiO3/PVDF composites show great potential for wearable electronics. Optimized processing conditions significantly enhanced the electroactive phase content, crucial for electromechanical applications.

Area of Science:

  • Materials Science
  • Polymer Science
  • Nanotechnology

Background:

  • Flexible piezoelectric fibers are key for next-generation wearable electronics.
  • Barium titanate (BaTiO3)/polyvinylidene fluoride (PVDF) composites offer desirable lightweight and flexible properties.
  • Enhancing the electroactive phase content is critical for improved electromechanical response.

Purpose of the Study:

  • To prepare BaTiO3/PVDF composite fibers via melt spinning and thermal drawing.
  • To systematically investigate the effects of processing parameters on fiber crystallinity and phase transformation.
  • To optimize fiber composition and processing for enhanced piezoelectric properties.

Main Methods:

  • Melt spinning under an electrostatic field followed by thermal drawing.
Keywords:
barium titanatecomposite fibermelt spinningnanoparticlespiezoelectric materialpolyvinylidene fluoride

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  • Fourier transform infrared spectroscopy (FTIR) for phase analysis.
  • X-ray diffraction (XRD), differential scanning calorimetry (DSC), and electron microscopy for structural characterization.
  • Main Results:

    • Processing conditions significantly influence the phase transformation of PVDF from the α-phase to the β-phase.
    • Optimized fibers (1 wt.% BaTiO3, thermal stretching ratio of 5, stretching rate of 40 mm/min, 18 kV electric field) achieved 61.3% crystallinity and 95.5% β-phase content.
    • Controlled processing parameters are crucial for tailoring the crystalline structure and enhancing piezoelectric potential.

    Conclusions:

    • The developed BaTiO3/PVDF composite fibers exhibit significant potential for flexible electroactive applications.
    • Optimized processing routes are effective in maximizing the electroactive β-phase content in PVDF.
    • Further electromechanical characterization is necessary for complete device integration and performance assessment.