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Related Concept Videos

Raman Spectroscopy Instrumentation: Overview01:26

Raman Spectroscopy Instrumentation: Overview

A conventional Raman spectrophotometer includes a laser source, a sample holding system, a wavelength selector, and a detector.
The monochromatic laser source, typically using visible or near-infrared radiation, generates a highly focused beam of light. This light interacts with the molecules of the sample, scattering some of the light. Liquid and gaseous samples are usually tested in ordinary glass capillaries, while solids can be analyzed as powders packed in capillaries or as potassium...
Gas Chromatography: Overview of Detectors01:13

Gas Chromatography: Overview of Detectors

Detectors in gas chromatography (GC) help identify and quantify the components of a mixture by translating chemical properties into measurable signals, which are displayed on a chromatogram. Detectors can be categorized into two main types: destructive and non-destructive.
A non-destructive detector allows a sample to be analyzed without altering or consuming it, meaning the sample can be collected after detection for further analysis. Examples include thermal conductivity detectors and...
¹H NMR: Long-Range Coupling01:27

¹H NMR: Long-Range Coupling

The coupling interactions of nuclei across four or more bonds are usually weak, with J values less than 1 Hz. While these are usually not observed in spectra, the presence of multiple bonds along the coupling pathway can result in observable long-range coupling.
In alkenes, spin information is communicated via σ–π overlap, as seen in allylic (four-bond) and homoallylic (five-bond) couplings. These coupling interactions are stronger when the σ bond is parallel to the alkene π orbitals.
2D NMR: Homonuclear Correlation Spectroscopy (COSY)01:06

2D NMR: Homonuclear Correlation Spectroscopy (COSY)

Homonuclear correlation spectroscopy, or COSY, is a 2-dimensional NMR technique that provides information about coupled protons. Typically, the geminal and vicinal coupling are observed. For example, consider the COSY spectrum of ethyl acetate, where its 1D proton NMR spectrum is plotted along the vertical and horizontal axes with their corresponding chemical shift scale. Three spots on the diagonal corresponding to the three peaks in the 1D proton spectrum are called diagonal peaks. The COSY...
¹³C NMR: ¹H–¹³C Decoupling01:04

¹³C NMR: ¹H–¹³C Decoupling

The probability of having two carbon-13 atoms next to each other is negligible because of the low natural abundance of carbon-13. Consequently, peak splitting due to carbon-carbon spin-spin coupling is not observed in spectra. However, protons up to three sigma bonds away split the carbon signal according to the n+1 rule, resulting in complicated spectra.
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Gas Chromatography–Mass Spectrometry (GC–MS)01:14

Gas Chromatography–Mass Spectrometry (GC–MS)

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Related Experiment Video

Updated: Jun 17, 2026

Infrared Degenerate Four-wave Mixing with Upconversion Detection for Quantitative Gas Sensing
10:42

Infrared Degenerate Four-wave Mixing with Upconversion Detection for Quantitative Gas Sensing

Published on: March 22, 2019

Coherence-multiplexed FMCW spectroscopy for long-distance multi-point gas sensing.

Ning Xu, Xiutao Lou, Baosen Tian

    Optics Letters
    |June 15, 2026
    PubMed
    Summary
    This summary is machine-generated.

    We developed a novel long-range gas-sensing technique using coherence multiplexing with optical frequency-modulated continuous-wave (FMCW) spectroscopy. This method significantly extends sensing distances for distributed gas monitoring applications.

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    Area of Science:

    • Optoelectronics
    • Spectroscopy
    • Environmental Monitoring

    Background:

    • Traditional spectroscopic gas sensing faces limitations in range and spatial resolution.
    • Distributed sensing requires robust methods to overcome signal degradation over long distances.

    Purpose of the Study:

    • To develop a long-range, multi-point spectroscopic gas-sensing method.
    • To enhance the sensing distance and spatial resolution of optical frequency-modulated continuous-wave (FMCW) spectroscopy.

    Main Methods:

    • Incorporation of coherence multiplexing into FMCW spectroscopy.
    • Segmentation of the sensing region to suppress phase noise accumulation.
    • Segment-by-segment adjustment of optical delay for optimal coherence matching.

    Main Results:

    • Demonstrated multi-point acetylene gas sensing over 11 km.
    • Achieved a minimum detectable concentration of 0.94 ppm and spatial resolution of 0.46 m.
    • Extended the sensing range by a factor of 60 compared to conventional methods.

    Conclusions:

    • The proposed coherence-multiplexed FMCW spectroscopy offers a low-cost, high-capacity solution for long-distance distributed gas monitoring.
    • The system relaxes requirements on laser coherence, detection bandwidth, and computing power.
    • Potential to multiplex thousands of sensors with sufficient optical power budget.