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Ir doping induced phase transformation and morphological reconstruction of MnO2 for efficient alkaline water

Wenlan Hong1, Yu Shuai1, Shucheng Liu1

  • 1School of Physical Sciences, Guizhou University, Guiyang 550025, China. yliu9@gzu.edu.cn.

Chemical Communications (Cambridge, England)
|June 16, 2026
PubMed

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Activated manganese(IV) oxide can selectively oxidize allylic and benzylic alcohols via a radical intermediate mechanism. Primary allylic alcohols are oxidized to aldehydes, while secondary allylic alcohols yield ketones. The redox reaction of potassium permanganate with an Mn(II) salt such as manganese sulfate (under either alkaline or acidic conditions), followed by thorough drying, yields the oxidizing agent: activated MnO2. While MnO2 is insoluble in the solvents used for the reaction, the...