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Structural Engineering and AgNO3 Modification toward High-Performance Thick Graphite Electrodes.

Yixuan Li1, Juntao Si1, Yida Wang1

  • 1CAS Key Laboratory of Precision and Intelligent Chemistry, Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, Anhui, China.

ACS Applied Materials & Interfaces
|June 16, 2026
PubMed
Summary
This summary is machine-generated.

Researchers developed a novel thick graphite electrode for lithium-ion batteries. This strategy enhances energy density by improving ion transport and lithium distribution, boosting performance.

Keywords:
AgNO3 modificationLi-ion batterygraphitephase inversion methodthick electrodes

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Energy Storage

Background:

  • Thick electrodes are key for high energy density lithium-ion batteries.
  • Challenges include slow ion transport and uneven lithium reactions in thick graphite electrodes, leading to performance issues.

Purpose of the Study:

  • To enhance the electrochemical performance of thick graphite electrodes.
  • To overcome limitations of sluggish ion transport and inhomogeneous lithium intercalation.

Main Methods:

  • Constructed vertically aligned channels using phase inversion for improved electrolyte infiltration and ion transport.
  • Applied interfacial chemical modification by impregnating AgNO3 to homogenize lithium-ion distribution.

Main Results:

  • Achieved accelerated activation and enhanced rate capability (339.2 mAh g⁻¹ at 1C, 237.3 mAh g⁻¹ at 2C).
  • Demonstrated superior low-temperature performance (338.9 mAh g⁻¹ at 0 °C).
  • Reached a high areal capacity of 5.7 mAh cm⁻² with a mass loading of 15 mg cm⁻².

Conclusions:

  • The synergistic strategy effectively addresses challenges in thick graphite electrodes.
  • This approach enables high-performance thick graphite electrodes for advanced lithium-ion batteries.