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Updated: Jun 18, 2026

Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators
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Isopentane Disproportionation in Lewis Acidic Chloroaluminate Ionic Liquid

Jiande Mai1,2, David E Ryan1,2, Wei Zhang1,2

  • 1Institute for Integrated Catalysis, Pacific Northwest National Laboratory, Richland, Washington 99354, United States.

Journal of the American Chemical Society
|June 17, 2026
PubMed
Summary

Ionic liquids catalyze alkane disproportionation via carbenium ions. Two kinetic regimes were observed, with the initial carbenium ion concentration significantly impacting isopentane conversion.

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