Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Theory of Attribution II: Kelley's Covariation Theory01:29

Theory of Attribution II: Kelley's Covariation Theory

Attribution theory plays a crucial role in social psychology, helping to explain how individuals interpret the causes of behavior. One prominent model within this field is Harold Kelley's covariation theory, which provides a systematic approach to determining whether internal traits or external circumstances drive a person's actions. The model posits that individuals rely on three key types of information—consensus, consistency, and distinctiveness—to make these judgments.Consensus: Comparing...
Theory of Attribution I: Correspondent Inference Theory01:15

Theory of Attribution I: Correspondent Inference Theory

Correspondent inference theory, proposed by Jones and Davis in 1965, seeks to explain how individuals infer stable personality traits from observed behaviors. It suggests that people attribute actions to underlying dispositions rather than external circumstances, particularly when the behavior appears intentional and socially significant.Voluntary Behavior and Dispositional AttributionAccording to this theory, individuals are more likely to attribute behavior to personal traits when it appears...
Attribution Theory00:56

Attribution Theory

Behavior is a product of both the situation (e.g., cultural influences, social roles, and the presence of bystanders) and of the person (e.g., personality characteristics). Subfields of psychology tend to focus on one influence or behavior over others. Situationism is the view that our behavior and actions are determined by our immediate environment and surroundings. In contrast, dispositionism holds that our behavior is determined by internal factors (Heider, 1958). An internal factor is an...
Fundamental Attribution Error01:14

Fundamental Attribution Error

According to some social psychologists, people tend to overemphasize internal factors as explanations—or attributions—for the behavior of other people. They tend to assume that the behavior of another person is a trait of that person, and to underestimate the power of the situation on the behavior of others. They tend to fail to recognize when the behavior of another is due to situational variables, and thus to the person’s state. This erroneous assumption is called the fundamental attribution...
Social Foundations of Self II: The Generalized Other01:20

Social Foundations of Self II: The Generalized Other

According to George Herbert Mead, as children progress beyond the game stage, they develop a more comprehensive understanding of societal rules and norms. This cognitive and social development enables them to internalize the expectations of the broader community, refining their ability to regulate behavior.Consistent participation in organized activities is crucial in helping children recognize that their actions are not isolated but contribute to a more significant, interconnected group effort.
Implicit Personality Theories01:23

Implicit Personality Theories

Implicit personality theory explains how individuals make assumptions about the relationships between personality traits, behaviors, and character types. When people learn that someone possesses a particular trait, they tend to infer the presence of other related characteristics, forming a cohesive impression. This cognitive shortcut plays a crucial role in social interactions and interpersonal judgments.Central Traits and Their InfluenceSolomon Asch's seminal 1946 study highlighted the power...

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

The fine effects of high magnetic fields on hyperfine shifts.

Chemical science·2026
Same author

Effect of Long-Term Contraception with Altrenogest in Dolphins (<i>Tursiops truncatus</i>).

Animals : an open access journal from MDPI·2026
Same author

General Spin Restricted Open-Shell Configuration Interaction Singles (GS-ROCIS): Implementation of Spin-Orbit Coupling and Zeeman Operators for Calculation of Optical and X-ray Absorption and Magnetic Circular Dichroism Spectra of Magnetically Coupled Transition Metal Systems.

The journal of physical chemistry. A·2025
Same author

Applications of Fast Iterative Filtering in NMR Spectroscopy: Baseline Correction.

Magnetic resonance in chemistry : MRC·2025
Same author

Treating Spin-Orbit Coupling and Spin-Spin Coupling in the Framework of the Iterative Configuration Expansion Selected CI.

Journal of chemical theory and computation·2025
Same author

Extracting Trends From NMR Data With TrAGICo: A Python Toolbox.

Magnetic resonance in chemistry : MRC·2025
Same journal

Data-Derived Conceptual DFT Nucleophilicity Index.

The journal of physical chemistry. A·2026
Same journal

Interconversion Mechanisms in H<sub>2</sub>N-O-NH<sub>2</sub>: Rotamerism, Pyramidal Inversion, or Akamptisomerism?

The journal of physical chemistry. A·2026
Same journal

Interpretable Machine Learning of Nanoparticle Stability through Topological Layer Embeddings.

The journal of physical chemistry. A·2026
Same journal

Magic Cluster Anion LaCu<sub>12</sub><sup>-</sup>: From Superatomic Electronic Structure to Spherical Aromaticity.

The journal of physical chemistry. A·2026
Same journal

High-Accuracy Extrapolated Ab Initio Thermochemistry of C<sub>3</sub>O, HC<sub>3</sub>O<sup>+</sup>, C<sub>3</sub>S, and HC<sub>3</sub>S<sup></sup>.

The journal of physical chemistry. A·2026
Same journal

Hydrogen Adsorption on Transition-Metal-Decorated Graphene: Thermodynamic and AIMD Insights from DFT and Post-Hartree-Fock Methods.

The journal of physical chemistry. A·2026
See all related articles

Related Experiment Video

Updated: Jun 19, 2026

Continuous Theta Burst Stimulation of the Posterior Medial Frontal Cortex to Experimentally Reduce Ideological Threat Responses
06:42

Continuous Theta Burst Stimulation of the Posterior Medial Frontal Cortex to Experimentally Reduce Ideological Threat Responses

Published on: September 28, 2018

Generalization of Bleaney's Theory.

Lucas Lang1, Bryan Lauw1, Letizia Fiorucci2

  • 1Technische Universität Berlin, Institut für Chemie, Theoretische Chemie/Quantenchemie, Sekr. C7, Straße des 17. Juni 135, 10623 Berlin, Germany.

The Journal of Physical Chemistry. A
|June 18, 2026
PubMed
Summary
This summary is machine-generated.

This study unifies magnetic property theories for paramagnetic species, offering accurate NMR chemical shifts and magnetic susceptibility calculations for transition-metal and lanthanide complexes. The generalized approach improves upon existing inverse-temperature expansion methods.

Related Experiment Videos

Last Updated: Jun 19, 2026

Continuous Theta Burst Stimulation of the Posterior Medial Frontal Cortex to Experimentally Reduce Ideological Threat Responses
06:42

Continuous Theta Burst Stimulation of the Posterior Medial Frontal Cortex to Experimentally Reduce Ideological Threat Responses

Published on: September 28, 2018

Area of Science:

  • Physical Chemistry
  • Quantum Chemistry
  • Solid State Physics

Background:

  • Bleaney's theory and inverse-temperature expansions are crucial for understanding magnetic properties of paramagnetic species.
  • Existing models have limitations, particularly for NMR chemical shifts beyond the point-dipole approximation and for lanthanide complexes.

Purpose of the Study:

  • To generalize and unify Bleaney's theory and related inverse-temperature expansions.
  • To derive an analytical equation for the 1/T^3 term in magnetic property expansions.
  • To investigate the convergence behavior of inverse-temperature expansions through numerical implementation of higher-order terms.

Main Methods:

  • Generalization and unification of existing theoretical frameworks.
  • Derivation of analytical equations for higher-order terms (specifically 1/T^3).
  • Numerical implementation of higher-order terms to assess convergence.

Main Results:

  • The generalized approach is valid for various properties, including NMR chemical shifts beyond the point-dipole approximation.
  • Accurate results for zero-field splittings in transition-metal complexes are achieved with second- and third-order expansions.
  • A newly derived third-order term significantly enhances accuracy for lanthanide complex susceptibility anisotropies.

Conclusions:

  • The unified approach provides a more accurate and broadly applicable method for calculating magnetic properties of paramagnetic species.
  • The derived analytical and numerical methods improve upon Bleaney's second-order theory, especially for lanthanide systems.
  • This work offers improved theoretical tools for both transition-metal and lanthanide chemistry research.