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Updated: Jun 20, 2026

An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
Published on: December 4, 2017
Macroscopic fluctuation theory of interacting Brownian particles
Aurélien Grabsch1, Davide Venturelli1, Olivier Bénichou1
1Laboratoire de Physique Théorique de la Matière Condensée (LPTMC), CNRS, Sorbonne Université, 4 Place Jussieu, 75005 Paris, France.
None:
We apply the macroscopic fluctuation theory (MFT) to study the large-scale dynamical properties of Brownian particles with arbitrary pairwise interaction. By combining it with standard results of equilibrium statistical mechanics for the collective diffusion coefficient, the MFT gives access to the exact large-scale dynamical properties of the system, both in and out of equilibrium. In particular, we obtain exact results for dynamical correlations between the density and the current of particles. For one-dimensional systems, this allows us to obtain a precise description of these correlations for emblematic models, such as the Calogero and Riesz gases, and for systems with nearest-neighbor interactions such as the Rouse chain of hardcore particles or the recently introduced model of tethered particles. Tracer diffusion with the single-file constraint (but for arbitrary pairwise interaction) is also studied. For higher-dimensional systems, we quantitatively characterize these dynamical correlations by relying on standard methods such as the virial expansion.
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