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Synthesis and Characterization of Self-Assembled Metal-Organic Framework Monolayers Using Polymer-Coated Particles
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Synthesis and Characterization of Self-Assembled Metal-Organic Framework Monolayers Using Polymer-Coated Particles

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Smart metal-organic framework/polymer composites: Different stimuli and applications.

Sina Ramezanian1, Milad Babazadeh-Mamaqani2, Moein Mohammadi-Jorjafki2

  • 1Chemical Engineering Faculty, Sahand University of Technology, P. O. Box 51335-1996, Tabriz, Iran; Transport Phenomena Research Center, Chemical Engineering Faculty, Sahand University of Technology, P.O. Box 51335/1996, Tabriz, Iran.

Advances in Colloid and Interface Science
|June 19, 2026
PubMed
Summary

Smart metal-organic framework (MOF)/polymer composites combine MOF porosity with polymer flexibility. These advanced materials overcome MOF limitations, enabling diverse applications in sensing, energy, and biomedicine.

Keywords:
Drug deliveryEnergy applicationsMetal-organic frameworksSensorsSmart MOF/polymer compositesStimuli-responsive polymersWaste water treatment

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Area of Science:

  • Materials Science
  • Nanotechnology
  • Polymer Science

Background:

  • Metal-organic frameworks (MOFs) offer high porosity and stability but face synthesis and solubility challenges.
  • Smart polymers exhibit stimulus-responsive behavior, expanding material functionalities.
  • Combining MOFs and polymers creates advanced composites with enhanced properties.

Purpose of the Study:

  • To review recent advancements in smart MOF/polymer composites.
  • To highlight the development of responsive MOFs for diverse applications.
  • To explore strategies for overcoming MOF limitations through hybridization.

Main Methods:

  • Review of literature on MOF/polymer composite synthesis and applications.
  • Analysis of material properties, including porosity, stability, and responsiveness.
  • Exploration of functional group manipulation and structural optimization techniques.

Main Results:

  • Smart MOF/polymer composites integrate MOF porosity with polymer flexibility.
  • These composites address limitations such as poor solubility and electrical properties.
  • Responsive MOFs demonstrate versatility in biomedical, environmental, energy, and sensing fields.

Conclusions:

  • Hybrid MOF/polymer composites offer multifunctional advantages.
  • Tailoring MOF and polymer components enhances material performance.
  • This interdisciplinary approach advances smart materials for complex challenges.