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Updated: Jun 21, 2026

Synthesis and Characterization of Self-Assembled Metal-Organic Framework Monolayers Using Polymer-Coated Particles
Published on: June 14, 2024
Smart metal-organic framework/polymer composites: Different stimuli and applications.
Sina Ramezanian1, Milad Babazadeh-Mamaqani2, Moein Mohammadi-Jorjafki2
1Chemical Engineering Faculty, Sahand University of Technology, P. O. Box 51335-1996, Tabriz, Iran; Transport Phenomena Research Center, Chemical Engineering Faculty, Sahand University of Technology, P.O. Box 51335/1996, Tabriz, Iran.
Smart metal-organic framework (MOF)/polymer composites combine MOF porosity with polymer flexibility. These advanced materials overcome MOF limitations, enabling diverse applications in sensing, energy, and biomedicine.
Area of Science:
- Materials Science
- Nanotechnology
- Polymer Science
Background:
- Metal-organic frameworks (MOFs) offer high porosity and stability but face synthesis and solubility challenges.
- Smart polymers exhibit stimulus-responsive behavior, expanding material functionalities.
- Combining MOFs and polymers creates advanced composites with enhanced properties.
Purpose of the Study:
- To review recent advancements in smart MOF/polymer composites.
- To highlight the development of responsive MOFs for diverse applications.
- To explore strategies for overcoming MOF limitations through hybridization.
Main Methods:
- Review of literature on MOF/polymer composite synthesis and applications.
- Analysis of material properties, including porosity, stability, and responsiveness.
- Exploration of functional group manipulation and structural optimization techniques.
Main Results:
- Smart MOF/polymer composites integrate MOF porosity with polymer flexibility.
- These composites address limitations such as poor solubility and electrical properties.
- Responsive MOFs demonstrate versatility in biomedical, environmental, energy, and sensing fields.
Conclusions:
- Hybrid MOF/polymer composites offer multifunctional advantages.
- Tailoring MOF and polymer components enhances material performance.
- This interdisciplinary approach advances smart materials for complex challenges.

