Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Metallic Solids02:37

Metallic Solids

Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability. Many...
Properties of Organometallic Compounds01:23

Properties of Organometallic Compounds

Organometallic compounds are compounds that contain a carbon–metal bond. Carbon belongs to an organyl group like alkyl, aryl, allyl, or benzyl groups. The metal can be from Group I or Group II of the periodic table, a transition metal, or a semimetal.

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Photoreforming of solid waste on 1 m<sup>2</sup> scale using single-source precursor-derived co-catalyst films.

Nature chemical engineering·2026
Same author

Hierarchical Environmental Exposure Transforms Zeolitic Imidazolate Framework-8 and Increases Toxicity in <i>Daphnia magna</i>.

ACS nano·2026
Same author

Evolution of Charge and Orbital Ordering, and Cation Vacancy Ordering During Electrochemical Desodiation of Na<sub><i>x</i></sub>NiO<sub>2</sub>.

Journal of the American Chemical Society·2026
Same author

Operando Investigation of Mechanochemically Synthesized Ni-Based Metal-Organic Frameworks for Electrocatalytic Alcohol Oxidation.

ChemSusChem·2026
Same author

Biofouled Micro- and Nanoplastics as Reactive Platforms for Potentially Toxic Element Transformation.

Environmental science & technology·2026
Same author

A Transformation-First Roadmap for Safe and Sustainable Emerging Advanced Materials.

Accounts of materials research·2026
Same journal

Dual-Function Halide Exchange Strategy for Simultaneous Sn<sup>4+</sup> Elimination and Stability Enhancement in Pb-Sn Mixed Perovskite Solar Cells.

ACS nano·2026
Same journal

Vertically Stacked Indium Gallium Zinc Oxide-Based Three-Dimensional Integrated Circuits.

ACS nano·2026
Same journal

Tunable Nanoparticle Thin-Film Reveals Distance Dependence of Auger-Mediated Radiation Enhancement in Diffuse Midline Glioma.

ACS nano·2026
Same journal

G-Quadruplex Network Engineering in Ionogels: Realizing Robust Biosensing Interfaces for Plant Electrophysiology.

ACS nano·2026
Same journal

Announcing the 2026 <i>ACS Nano</i> Lectureship and <i>ACS Nano</i> Impact Award Laureates.

ACS nano·2026
Same journal

Ultrafast Self-Assembly of Zeolitic Imidazolate Framework-8 Enables Antibody Orientation for Ultrasensitive Lateral Flow Immunoassays.

ACS nano·2026
See all related articles

Related Experiment Video

Updated: Jun 24, 2026

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance
08:12

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance

Published on: September 5, 2018

Structural Persistence Masks Commit-Point Chemical Transformation in Copper-Imidazolate Nanosheet Metal-Organic

Swaroop Chakraborty1, Ana Guilherme Buzanich2, Prathmesh Bhadane3

  • 1School of Geography, Earth & Environmental Sciences, University of Birmingham, Edgbaston B15 2TT, U.K.

ACS Nano
|June 23, 2026
PubMed
Summary
This summary is machine-generated.

Copper-imidazolate (CuIm) metal-organic frameworks (MOFs) stability depends on their environment. CuIm transforms rapidly in complex media, showing early changes in chemical identity, not just structure.

Keywords:
X-ray absorption spectroscopymetal−organic frameworksrapid transformationsafe and sustainable by designtransformation kinetics

More Related Videos

Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
07:14

Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers

Published on: May 12, 2023

Synthesis and Characterization of Functionalized Metal-organic Frameworks
11:27

Synthesis and Characterization of Functionalized Metal-organic Frameworks

Published on: September 5, 2014

Related Experiment Videos

Last Updated: Jun 24, 2026

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance
08:12

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance

Published on: September 5, 2018

Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
07:14

Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers

Published on: May 12, 2023

Synthesis and Characterization of Functionalized Metal-organic Frameworks
11:27

Synthesis and Characterization of Functionalized Metal-organic Frameworks

Published on: September 5, 2014

Area of Science:

  • Environmental chemistry
  • Materials science
  • Nanotechnology

Background:

  • Metal-organic frameworks (MOFs) stability is crucial for applications.
  • Current stability assessments often use end-point metrics.
  • The chemical identity of MOFs can change over time in aqueous environments.

Purpose of the Study:

  • To investigate the transformation of nanoscale copper-imidazolate (CuIm) MOFs.
  • To understand MOF stability across different aqueous matrices.
  • To correlate structural changes with chemical identity evolution.

Main Methods:

  • Time-resolved speciation analysis of copper-centered species.
  • Separation of particle-associated and dissolved fractions.
  • Exposure of CuIm MOFs to borehole water, artificial seawater, and cell-culture medium.

Main Results:

  • CuIm MOFs showed matrix-dependent transformation rates.
  • Rapid transformation occurred in cell-culture medium within 4 hours.
  • Copper mobilization varied with matrix, indicating medium-specific reactivity.
  • Structural signatures can persist despite altered surface chemistry.

Conclusions:

  • CuIm MOF transformation follows matrix-selected trajectories with early shifts.
  • Stability assessments require time-resolved chemical identity analysis, not just end-point crystallinity.
  • Environmental conditions significantly impact MOF stability and behavior.