Rational Design of Deep Eutectic Solvent-Mediated MOF-Based Membranes for the Recovery of Pb(II) and Cr(III) Ions...

The sustainable recovery of high-value metals from wastewater has garnered significant attention in light of the circular economy and environmental preservation. Because of its appealing characteristics, membrane separation technology is essential for the sustainable and effective recovery of valuable metals from wastewater, in contrast to conventional methods, which are chemical- or energy-intensive. In this study, a rational design approach was utilized to synthesize a metal-organic framework (MOF) using a deep eutectic solvent (DES) as a mediating medium to control the reaction of framework formation and particle properties. While DESs have been widely used for the physical modification of materials, their role as a chemically modifying medium during MOF synthesis for structural tailoring remains less explored. This synthesized MOF (DM-Zn-PDC@MOF) was further introduced as filler in polysulfone (PSf)-based mixed matrix membranes (MMMs). The performance of DM-Zn-PDC@MOF within the polymer matrix was examined. Several characterization techniques were used to thoroughly analyze the morphological, chemical, and physical characteristics of the MMMs and DM-Zn-PDC@MOF. The addition of the filler material significantly enhanced the membrane characteristics, including pure water flux, hydrophilicity, porosity, surface roughness, pore size, and heavy metal resource recovery in comparison with the pristine membrane. Stable incorporation of the filler within the membrane matrix was indicated by much less filler leaching (<5%) at all concentrations. With DM-Zn-PDC@MOF loading, the pure water flux increasedmore than nine times from 102.8 L/m²h (M-0) to 971.5 L/m²h (M-4). The functionalized membranes showed better flux retention in high-value heavy metal resource recovery using simulated wastewater: 871.8 L/m²h when filtering a Pb(II) ion solution (compared to M-0 with flux 120.6 L/m²h) and 526.8 L/m²h when filtering a Cr(III) ion solution (compared to M-0 with flux 97.1 L/m²h). These values represented approximately 7-fold and 5-fold improvements, respectively. Overall, Pb⁺² > Cr⁺³, but the rejection of Cr(III) ions was also improved, when compared with M-0. The high flux of the membrane makes it easier to process large volumes and concentrate metals in the retentate, turning diluted contaminated streams into a concentrated feedstock for subsequent recovery procedures.