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Inhibiting selenium loss in sodium-selenium batteries via a Lewis acid-base dual-site host.

Rui Wang1, Guoqiang Yuan1, Lin Ding1

  • 1School of Chemistry and Materials, Yangzhou University, Yangzhou, 225002 Jiangsu, P. R. China. wtlichem@yzu.edu.cn.

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A novel nitrogen-doped carbon (NB@C) host material effectively anchors polyselenides, preventing active selenium loss and anode corrosion in sodium-selenium batteries. This design offers a general strategy for advanced selenium hosts.

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Energy Storage

Background:

  • Sodium-selenium (Na-Se) batteries are promising next-generation energy storage devices.
  • Polyselenide shuttling and active material loss are major challenges hindering Na-Se battery performance.
  • Corrosion of the sodium metal anode by polyselenides further degrades battery stability.

Purpose of the Study:

  • To design and synthesize a novel host material for Na-Se batteries.
  • To anchor polyselenides and mitigate anode corrosion.
  • To improve the overall performance and stability of sodium-selenium batteries.

Main Methods:

  • A nitrogen-doped carbon (NB@C) host material was designed.
  • The material combines Lewis acid-base properties to anchor polyselenides.
  • Electrochemical performance of Na-Se batteries utilizing the NB@C host was evaluated.

Main Results:

  • The NB@C host effectively anchored polyselenides, significantly inhibiting their shuttle effect.
  • Corrosion on the sodium metal anode was mitigated.
  • Improved cycling stability and capacity retention were achieved in Na-Se batteries.

Conclusions:

  • The designed NB@C host material demonstrates excellent performance in Na-Se batteries.
  • This work presents a general and effective doping strategy for advanced selenium hosts.
  • The findings contribute to the development of high-performance sodium-selenium batteries.