A Ferrocene Metal-Ligand Triplet Diradical with a Terminal Iminyl Group Discovered by Time-Resolved Mid-Infrared

Markus Bauer1, Oliver Pichl1, Frederik Scherz2

  • 1Clausius-Institut für Physikalische und Theoretische Chemie, Rheinische Friedrich-Wilhelms-Universität, Bonn 53177, Germany.

Summary

Researchers photochemically generated a unique ferrocene diradical from an azidoferrocene precursor. This metal-ligand diradical exhibits a triplet ground state and opens new avenues for magnetic materials and chemical reactivity.

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