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Published on: March 4, 2021
Does aurophilicity exist beyond the solid state?
Yury V Vishnevskiy1,2, Felix Müller1, Ivan Y Kurochkin3
1Lehrstuhl für Anorganische Chemie und Strukturchemie (ACS), Fakultät für Chemie, Universität Bielefeld, Universitätsstraße 25, 33615 Bielefeld, Germany. VishnevskiyYV@my.msu.ru.
Abstract:
The first experimental gas-phase structure exhibiting aurophilic Au(I)···Au(I) interactions was determined by electron diffraction for the o-dimethylphosphanyl(perfluorophenylene)gold(I) dimer. The Au···Au contact is shorter than in the crystal structure, providing direct gas-phase evidence for an aurophilic attraction in a ligand-supported molecular system. High-level relativistic coupled-cluster calculations reproduce the experimental gas-phase value.
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