Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

A<sub>3</sub>Zr<sub>2</sub>(PS<sub>4</sub>)(P<sub>2</sub>S<sub>7</sub>)<sub>2</sub> (A = K, Rb, Cs) Synthesized by the Metal Oxide-Boron-Chalcogen Routine: A Series of Zirconium-Based Thiophosphate Nonlinear Optical Crystals Featuring PS<sub>4</sub> Tetrahedron and P<sub>2</sub>S<sub>7</sub> Dimer.

Inorganic chemistry·2026
Same author

Salt-Inclusion Rare-Earth Chalcogenides: Exploring Infrared Nonlinear Optical Crystals via a Guest-Framework Modulation Strategy.

Inorganic chemistry·2026
Same author

From KBa<sub>4</sub>Ge<sub>3</sub>S<sub>10</sub>Cl to ABa<sub>3</sub>EuGe<sub>3</sub>S<sub>11</sub> (A = Na, K) Synthesized by Reactive Flux Assisted Metal Oxide-Boron-Chalcogen (MOBQ) Method: Effect of Cation/Anion Cosubstitution on Crystal Structure and Nonlinear Optical Properties.

Inorganic chemistry·2026
Same author

Point-to-volume engineering enables enhanced birefringence and a wide bandgap in hybrid halide ultraviolet nonlinear optical crystals.

Chemical science·2026
Same author

Regulating KBBF-like structures <i>via</i> a charge-assisted hydrogen-bonded framework to enable easily grown ultraviolet nonlinear optical crystals.

Chemical science·2026
Same author

<i>Rhododendron mulunense</i> (Ericaceae), a new species from the karst mountains of Guangxi and Guizhou provinces, China.

PhytoKeys·2026

Related Experiment Video

Updated: Jul 6, 2026

A Technical Guide for Performing Spectroscopic Measurements on Metal-Organic Frameworks
10:13

A Technical Guide for Performing Spectroscopic Measurements on Metal-Organic Frameworks

Published on: April 28, 2023

Nonlinear Optical-Active NaAlP2S6 Synthesized by the MOBQ Method: Synthesis, Structure, and Optical Properties.

Zong-Ze Li1, Zheng-Ren Chen1, Sheng-Ping Guo1,2

  • 1Yunnan Key Laboratory of Electromagnetic Materials and Devices, School of Materials and Energy, Yunnan University, Kunming 650500, P. R. China.

Inorganic Chemistry
|July 4, 2026
PubMed
Summary

A new aluminum-based material, NaAlP2S6, was synthesized for nonlinear optical (NLO) applications. This thiophosphate exhibits a wide bandgap and ultrahigh laser-induced damage threshold, showing promise for NLO crystal development.

More Related Videos

Spectral and Angle-Resolved Magneto-Optical Characterization of Photonic Nanostructures
08:01

Spectral and Angle-Resolved Magneto-Optical Characterization of Photonic Nanostructures

Published on: November 21, 2019

Microwave-assisted Intramolecular Dehydrogenative Diels-Alder Reactions for the Synthesis of Functionalized Naphthalenes/Solvatochromic Dyes
12:07

Microwave-assisted Intramolecular Dehydrogenative Diels-Alder Reactions for the Synthesis of Functionalized Naphthalenes/Solvatochromic Dyes

Published on: April 1, 2013

Related Experiment Videos

Last Updated: Jul 6, 2026

A Technical Guide for Performing Spectroscopic Measurements on Metal-Organic Frameworks
10:13

A Technical Guide for Performing Spectroscopic Measurements on Metal-Organic Frameworks

Published on: April 28, 2023

Spectral and Angle-Resolved Magneto-Optical Characterization of Photonic Nanostructures
08:01

Spectral and Angle-Resolved Magneto-Optical Characterization of Photonic Nanostructures

Published on: November 21, 2019

Microwave-assisted Intramolecular Dehydrogenative Diels-Alder Reactions for the Synthesis of Functionalized Naphthalenes/Solvatochromic Dyes
12:07

Microwave-assisted Intramolecular Dehydrogenative Diels-Alder Reactions for the Synthesis of Functionalized Naphthalenes/Solvatochromic Dyes

Published on: April 1, 2013

Area of Science:

  • Materials Science
  • Solid-State Chemistry
  • Optoelectronics

Background:

  • Group 13 metal chalcogenides are vital infrared nonlinear optical (NLO) crystals.
  • Group 13 metal chalcophosphates, especially Al-based, are underexplored.
  • Al-based functional motifs hold potential for advanced NLO applications.

Purpose of the Study:

  • To synthesize and characterize a novel quaternary thiophosphate, NaAlP2S6.
  • To investigate the structural and NLO properties of NaAlP2S6.
  • To explore the potential of Al-based chalcophosphates for NLO applications.

Main Methods:

  • Synthesis via reactive flux NaCl-assisted metal oxide-boron-chalcogen (MOBQ) solid-state method.
  • Crystallographic analysis to determine the orthorhombic Fdd2 structure.
  • Experimental and theoretical calculations to evaluate optical properties and NLO response.

Main Results:

  • NaAlP2S6 crystallizes in a 3D framework of AlS6 octahedra and P2S6 dimers.
  • The material exhibits a wide bandgap (3.72 eV) and a moderate second harmonic generation (SHG) response (0.25 × AgGaS2).
  • NaAlP2S6 demonstrates an ultrahigh laser-induced damage threshold (LIDT) of 14.7 × AgGaS2.

Conclusions:

  • NaAlP2S6 is a promising new material for NLO applications.
  • The P2S6 dimers are the primary contributors to the SHG response.
  • Al-based chalcophosphates represent a new avenue for designing high-performance NLO crystals.