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Updated: Jul 10, 2026

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Dual-Functional Smart Coating Based on Water-Based Polyaniline Composites for Active Corrosion Protection and

Xinyue Xiang1, Yaning Wang1, Xincui Shi1

  • 1School of Chemistry & Environmental Engineering, Jilin Provincial International Joint Research Center of Photo-Functional Materials and Chemistry, Changchun University of Science and Technology, Changchun 130022, China.

Langmuir : the ACS Journal of Surfaces and Colloids
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PubMed
Summary

This study introduces a smart water-based coating using polyaniline and polydopamine nanoparticles. The innovative coating offers enhanced corrosion protection and visual damage detection, with potential for self-healing applications.

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Area of Science:

  • Materials Science
  • Corrosion Science
  • Nanotechnology

Background:

  • Water-based anticorrosion coatings face challenges with hydrophilicity and microcracking, limiting their performance.
  • Developing sustainable coatings with advanced functionalities is crucial for industrial applications.

Purpose of the Study:

  • To develop a water-based smart coating with active corrosion protection and real-time damage visualization.
  • To investigate the impact of microcapsule contents on coating dispersion and anticorrosion properties.
  • To explore the photothermal response and potential self-healing capabilities of the developed coating.

Main Methods:

  • Encapsulation of photothermal-responsive polydopamine nanoparticles and fluorescent indicators within polyaniline-shell microcapsules.
  • Formulation of a water-based coating incorporating poly(vinyl alcohol) and polystyrenesulfonate to improve dispersion.
  • Electrochemical impedance spectroscopy and UV irradiation tests to evaluate anticorrosion performance and photothermal effects.

Main Results:

  • Incorporation of poly(vinyl alcohol) and polystyrenesulfonate significantly improved polyaniline dispersion in the aqueous system.
  • The PD@PANI/P-PVA coating demonstrated enhanced anticorrosion performance, with impedance modulus increasing by two orders of magnitude after 20 days of immersion.
  • UV irradiation induced a significant temperature increase, indicating photothermal potential for defect repair and triggered release.

Conclusions:

  • The developed water-based smart coating offers improved dispersion, enhanced corrosion protection, and real-time damage visualization.
  • The coating exhibits preliminary self-healing capability and stimulus-responsive functionality via a synergistic photothermal effect.
  • The smart coating shows significant potential for applications in shipping, construction, and other corrosive environments.