Continuous thermodynamics approach for hydrogen solubility prediction

Accurate characterization of heavy petroleum fractions remains challenging in hydroprocessing reactor modeling, where reliable hydrogen-solubility estimates in complex hydrocarbon mixtures are essential. Continuous thermodynamics has been successfully applied to represent crude oils and petroleum fractions in vapour-liquid equilibrium calculations through continuous composition distributions. Building on this framework, we propose a continuous-thermodynamics-based characterization methodology for vacuum gas oils and integrate it with the Augmented Grayson-Streed (AGS) approach to predict hydrogen solubility. Over temperature and pressure ranges of 459-653 K and 1.0-12.5 MPa, respectively, the proposed strategy reduces the global average absolute deviation with respect to experimental data from 22.5% to 11%. Beyond improving accuracy, the framework provides a systematic route to define a minimal set of pseudocomponents, reducing arbitrariness in heavy-fraction characterization while relying only on routinely measured laboratory data.