Synthesis of Fe₂O₃/γ-Al₂O₃ via Sol-Gel Method for Congo Red Adsorption: Kinetic Analysis and DFT Insights

With the growing emphasis on environmental sustainability, the proper treatment of industrial wastewater and the protection of groundwater resources have become pressing global concerns. Congo red (CR), a widely used azo dye, enters water bodies via wastewater discharge, posing persistent ecological risks to surface and groundwater systems. Adsorption, as a direct and sustainable remediation approach, necessitates the development of high-performance adsorbents to inhibit CR migration into groundwater. In this study, a Fe₂O₃/γ-Al₂O₃ composite was synthesized via sol-gel method for efficient CR adsorption, thereby mitigating groundwater contamination risk. The composite exhibited a high specific surface area (246.22 m²/g) and a maximum adsorption capacity of 1027.72 mg/g. Adsorption behavior followed the pseudo-second-order kinetic and Langmuir isotherm models, consistent with chemisorption-driven monolayer adsorption. The Weber-Morris intraparticle diffusion model confirmed rapid initial surface adsorption, beneficial for practical groundwater remediation. pH-dependent adsorption efficiency further indicated the role of electrostatic interactions, informing process optimization under varying groundwater chemistries. DFT calculations demonstrated that Fe₂O₃/γ-Al₂O₃ possesses a higher adsorption affinity for CR than γ-Al₂O₃. Collectively, Fe₂O₃/γ-Al₂O₃ shows strong potential as a novel, efficient adsorbent for CR interception and groundwater quality protection.