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Updated: Jul 15, 2026

Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
Published on: June 7, 2018
Electric current as a stabilizing thermodynamic field in metallic crystals
Shubhayan Mukherjee1, Wan-Zhen Hsieh2, Yu-Chen Liu3,4,5
1Department of Materials Science and Engineering, National Cheng Kung University, Tainan, Taiwan, ROC.
Abstract:
Electric current is typically associated with electromigration damage, but under steady current-carrying conditions it can also bias lattice stability. Here, in situ synchrotron X-ray diffraction and nanodiffraction show that a current density of A cm-2 retains hexagonal η-Cu6Sn5 under conditions where temperature-matched thermal treatment drives the η → η' transformation. The retained η phase accommodates the current through anisotropic elastic distortion, with c-axis expansion of ~1.3% and basal-plane contraction of ~0.8%, accompanied by plane-selective dislocation rearrangement and partial lattice recovery after current removal. Grain-resolved stress/strain mapping yields a spatially averaged post-ECS principal-stress scale of ~30-40 MPa, consistent with an order-of-magnitude electron-wind estimate, while the associated elastic-energy density of 9-12 MJ m-3 remains well below the reconstructive barrier of ~150 MJ m-3. These results identify a phenomenological electron-wind-driven elastic accommodation regime in η-Cu6Sn5 under the present current density and experimental geometry, accompanied by plane-selective defect rearrangement, and are experimentally consistent with a Gibbs-like description of the current-carrying steady state.
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