Optimizing Strength and Post-Peak Ductility in Sustainable Concretes: The Synergy of Silica Fume and Nano-Silica with...

The modification of cementitious binders using active mineral additives and nano-components represents a crucial pathway for developing high-performance, sustainable concrete composites. Nevertheless, unilateral modification of the matrix with highly reactive siliceous materials often leads to an undesirable increase in composite brittleness. This study investigates the synergistic effect of the concurrent application of nano-silica (NS), silica fume (SF), and Class F fly ash (FA) in ternary and quaternary binders, aimed at optimizing both load-bearing capacity and fracture toughness. The experimental program was conducted on seven concrete series, evaluating their mechanical parameters and non-linear fracture properties using the two-parameter fracture model (TPFM) on notched beams subjected to three-point bending. Additionally, a high-resolution energy partitioning framework was applied, decomposing the total fracture energy into four distinct components-fracture initiation energy in the elastic range (G_ini), pre-peak microcracking energy (G_pre), main material softening energy (G_soft), and residual tail energy dissipated at large crack openings (G_tail)-along with the determination of the characteristic length (l_ch). The results demonstrated that while purely siliceous systems (modified with NS and SF) generate high strength increments, they simultaneously trigger a "brittleness trap," manifested by a 13.65% decrease in the l_ch parameter. The introduction of FA effectively mitigates this hazard, transforming the failure mode into a quasi-ductile behavior. The concrete series modified with the NS+FA hybrid (Mix-5) exhibited a spectacular 107% increase in G_f and an increase in l_ch of nearly 50%, while maintaining high fracture toughness. Energy decomposition analysis in quaternary concretes confirmed a desirable reduction in the initiation energy share in favor of the softening and tail phases (G_tail reaching a record 13.1% for Mix-7), suggesting the probable activation of macroscopic crack-bridging mechanisms driven by the delayed hydration of FA particles. The research indicates that precise design of multi-component binders allows for achieving an optimal technological equilibrium point-the "sweet spot"-combining high structural capacity with safe material ductility.