Research Progress of Pyroelectric Nanogenerator and Its Hybrid Nanogenerators

Pyroelectric nanogenerators (PyNGs) have attracted extensive attention for converting thermal energy into electricity, yet their low output power remains a critical bottleneck hindering practical use. This review summarizes various pyroelectric materials and device structures, elucidates the working principle, and discusses their output performances and application scenarios. The correlation between device output and key factors, including intrinsic material properties, electrode dimensions, and external thermal excitation, is systematically examined. Hybrid nanogenerators (HNGs) that couple pyroelectric with piezoelectric, triboelectric, and photovoltaic effects are also reviewed. In addition, the evaluation criteria for pyroelectric energy conversion efficiency are examined, highlighting the need for more systematic studies in this aspect. Finally, key challenges and corresponding strategies are discussed to facilitate the practical deployment of PyNGs in areas such as wearable electronics and self-powered sensors.