Microscopic origins of electron trapping in amorphous silicon nitride (a-Si₃N₄) and its role in charge-trap flash...

Amorphous silicon nitride (-SiN) is widely used as the charge storage layer of charge-trap flash (CTF) memory devices, where its high density of deep localized electronic states enables long-term data retention at room temperature. Despite its technological relevance, the microscopic nature of the charge traps in-SiNis still controversial. In recent years, atomistic modeling has enabled the characterization of intrinsic defects in, providing new insights into their structural and electronic properties that are comprehensively discussed in this review. We demonstrate that a variety of structural irregularities, including over- and undercoordinated atoms,bonds, vacancies and strainedbonds, introduce localized electronic states in the amorphous network, which act as precursor sites for trapping and retaining electrons. The associated charge transition processes at these trapping sites are analyzed within the framework of nonradiative multiphonon theory and evaluated in the context of macroscopic CTF functionality. Additionally, we present a density functional theory-based computational approach to estimate electron capture cross sections of intrinsic defect sites in.