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Published on: June 7, 2019
Electrochemical Control of Tunable Infrared Nanocrystal Metasurfaces
Woo Je Chang1,2, Zarko Sakotic3, Madeline Brown3
1McKetta Department of Chemical Engineering, University of Texas at Austin, Austin, Texas78712, United States.
ACS Nano
|July 20, 2026
Summary
Researchers developed novel dynamic metasurfaces using nanocrystals for mid-infrared light control. These materials offer electrochemically switchable optical responses, enabling advanced applications in imaging and signal processing with high modulation efficiency.
Area of Science:
- Photonics and Materials Science
- Nanotechnology
- Mid-Infrared Optics
Background:
- Dynamic control of photonic materials at mid-infrared wavelengths is crucial for applications like thermal management and active imaging.
- Current methods using metasurfaces or ultrathin materials face scalability and light-matter interaction challenges.
Purpose of the Study:
- To demonstrate electrochemically switchable dynamic metasurfaces with tunable linear and nonlinear optical responses.
- To achieve strong light modulation within small volumes using colloidal nanocrystal assemblies.
Main Methods:
- Fabrication of cavity-coupled assemblies of sub-10 nm plasmonic tin-doped indium oxide nanocrystals.
- Integration of colloidal nanocrystals into a photonic architecture for enhanced light-matter interaction.
- Electrochemical switching to control permittivity and electromagnetic fields.
Main Results:
- Achieved 77% absolute reflection modulation in dynamic metasurfaces.
- Demonstrated spectrally selective responses across 2.5-4 μm via tin doping.
- Exhibited electrically switchable ultrafast nonlinear optical response with 0.25 ps recovery time.
Conclusions:
- Cavity-coupled nanocrystal assemblies serve as effective dynamic metasurfaces with tunable optical properties.
- Solution processing enables centimeter-scale device uniformity and scalability.
- The developed materials enable dual-time scale optical control for advanced photonic applications.

