Related Experiment Video
Updated: Aug 6, 2026

An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
Published on: December 4, 2017
Rigorous Bound on Hydrodynamic Diffusion for Chaotic Open Spin Chains
Dimitrios Ampelogiannis1, Benjamin Doyon1
1Department of Mathematics, King's College London, Strand, London, WC2R 2LS UK.
Abstract:
The emergence of diffusion is one of the deepest physical phenomena observed in many-body interacting, chaotic systems. But establishing rigorously that correlation functions, say of the spin, expand diffusively, remains one of the most important problems of mathematical physics. We establish for the first time, with Lindbladian evolution, a lower bound on spin diffusion in chaotic, translation-invariant, nearest-neighbor open quantum spin-1/2 chain satisfying a local unitality condition and strong conservation of magnetization. The bound is strictly positive if and only if the local quantum jumps transport spin. Physically, the bound comes from the spreading effects of initial-state macroscopic fluctuations, a mechanism which occurs whenever spin is an interacting ballistic mode. Chaoticity means that the Hilbert space of extensive charges is spanned by magnetization; we expect this to be generic. Our main tool is the Green-Kubo formula, the mathematical technique of projection over quadratically extensive charges, and appropriate correlation decay bounds recently established. Because Lindbladian dynamics is not reversible, the Green-Kubo spin diffusion strength includes a contribution due to irreversibility, which we interpret as encoding the hydrodynamic entropy production that may occur in the forgotten environment. This, we show, vanishes for certain choices of interaction parameters, for which the Lindbladian dynamics becomes reversible. Our methods can be extended to finite or short ranges, higher spins, and other non-Hamiltonian systems such as quantum circuits. As we argue, according to the theory of nonlinear fluctuating hydrodynamics, we further expect these systems to display superdiffusion, and thus have infinite diffusivity; however this appears to still be beyond the reach of mathematical rigor.
Related Concept Videos
Radical Chain-Growth Polymerization: Chain Branching
Radical Chain-Growth Polymerization: Mechanism
Spin–Spin Coupling Constant: Overview
Qualitatively, any spin plus-half nucleus polarizes the spins of its electrons to the minus-half state. Consequently, the paired electron in the hydrogen–carbon bond must have a...
Entropy Change in Reversible Processes
The statement can be further generalized to prove that entropy is a state function. Take a cyclic process between any two points on a p-V diagram.
Entropy and Solvation
Spin–Spin Coupling: One-Bond Coupling

