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Characterization of Thermal Transport in One-dimensional Solid Materials
Published on: January 26, 2014
Violation of local equilibrium thermodynamics in one-dimensional Hamiltonian-Potts model
Hitomi Endo1, Michikazu Kobayashi1
1Kochi University of Technology, School of Environmental Science and Engineering, Miyanoguchi 185, Tosayamada, Kami, Kochi 782-8502, Japan.
Abstract:
We investigate nonequilibrium phase coexistence associated with a first-order phase transition by numerically studying a one-dimensional Hamiltonian-Potts model with fractional spatial derivatives. The fractional derivative is introduced so as to reproduce the low-wave-number density of states of the standard two-dimensional model, allowing phase coexistence to occur in a minimal one-dimensional setting under steady heat conduction. By imposing a constant heat flux through boundary heat baths, we observe the stable coexistence of ordered and disordered phases separated by a stationary interface. We find that the temperature at the interface systematically deviates from the equilibrium transition temperature, demonstrating a clear violation of the local equilibrium description. This deviation indicates that equilibrium metastable states can be stabilized and controlled by a steady heat current. Furthermore, the interface temperature obtained in our simulations is in quantitative agreement with the prediction of global thermodynamics for nonequilibrium steady states. These results confirm that the breakdown of local equilibrium and the stabilization of metastable states are intrinsic features of nonequilibrium first-order phase transitions, independent of spatial dimensionality. Our study thus provides a minimal and controlled numerical model for exploring the fundamental limits of thermodynamic descriptions in nonequilibrium steady states.
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