Natural Si/N Co-Doped Porous Biomass Carbon Micron-Tubes as High-Performance Anode Materials for Lithium-Ion...

The development of carbon-based anode materials for high-performance lithium-ion batteries has been limited by their low theoretical capacity density, low conductivity, and high manufacturing costs. Herein, natural Si/N co-doped biomass carbon micron-tubes, derived from reed catkins, were synthesized. The as-prepared RC-Si/N anode exhibits a good discharge capacity of 761.3 mAh g^-1 at 100 mA g^-1 after 200 cycles. Moreover, it exhibits outstanding cycling stability, retaining discharge capacities of 517.7 mAh g^-1 at 1 A g^-1 after 1000 cycles. The excellent electrochemical performance is attributed to the trace Si originating from the biomass precursor, which provides high specific capacity, while N doping introduces structural defects and improves electronic conductivity. Coupled with its unique micrometer-scale tubular morphology, the material facilitates efficient lithium-ion transport and storage. Further DFT calculations corroborate enhanced Li⁺ adsorption ability, sustained structural integrity over prolonged cycling, and promoted reaction kinetics. These findings underscore the potential of natural Si/N co-doped biomass-derived carbon as an advanced lithium-ion battery anode material.