Occurrence, Source Apportionment and Health Risk Potential of Polycyclic Aromatic Hydrocarbons (PAHs) in Urban Soils...

Urban soils act as sinks for polycyclic aromatic hydrocarbons (PAHs) indicating the intensity of the anthropogenic load, while potential environmental and human health concerns may arise. In the present study, the concentrations, spatial distribution, source apportionment and potential health risks of 16 priority PAHs were investigated in urban soils from the city of Thessaloniki, Northern Greece. Surface soil samples were collected from 19 locations characterized by different land uses and traffic conditions. The total levels of the 16 PAHs exhibited substantial variability, with a range of 14.09-1565.4 μg kg^-1, reflecting heterogeneous contamination patterns across the city. PAH profiles were dominated by high-molecular-weight compounds (4-6 rings) accounting for over 80% of the total PAHs. Diagnostic molecular ratios highlighted pyrogenic sources, verifying that high-temperature combustion processes dominated the PAH inputs in the urban soils from Thessaloniki city. The factor score plot made prominent the presence of localized contamination hotspots in areas characterized by intense and continuous traffic activity, spotlighting vehicular traffic emissions and transport-related activities as primary sources of PAHs in the study area. Carcinogenic risk assessment based on the BaP-EQ approach indicated acceptable risk levels for most of the sampled soils, although limited localized hotspots with elevated carcinogenic risk were identified. This study provides important baseline information for understanding PAH contamination in urban environments and supports the development of targeted pollution mitigation and environmental management strategies.