Detection of Simulated Space Weathering on Electron Irradiated Water-Ice Coated Silicon Using AFM-IR, SEM, and S/TEM...

Space weathering causes physical and spectral changes on the surfaces of airless bodies. However, our understanding of how space weathering operates in the presence of volatile ices is in its early stages. Electron irradiation of ice-coated surfaces is expected in astrophysical environments including the early solar system, volatile ice-rich permanently shadowed regions of the Moon and Mercury, and other airless bodies like asteroids. A recent study suggests that anomalous oxygen isotope exchange occurs between water-ice and underlying surfaces when exposed to electron irradiation at extremely low temperatures (10 K). To delve deeper into the physical processes underlying isotopic exchange, we employ nanoscale atomic force microscopy-based infrared (AFM-IR) spectroscopy to identify Si-O bond formation resulting from the electron irradiation of H₂O ice coated silicon targets. Experimental variables include electron energy, amount and timing of water-ice deposition, and surface area exposed to the electron beam. AFM-IR point spectra, surface topography and IR absorption mapping reveal that the degree of surface oxidation is dependent upon experimental conditions. Scanning electron microscopy and (scanning) transmission electron microscope imaging confirm the formation of thicker SiO _x in regions of enhanced interaction between electron irradiation, water-ice, and the silicon substrate. In summary, we find that electron irradiation with energies as low as 1 keV/electron can break the chemical bonds of refractory solids like Si under these simulated cold astrophysical conditions. These results suggest that cosmic rays may play a more significant role than previously thought in the chemical evolution of dust grains in cold astrophysical and protoplanetary environments.